| 1 | Gray, Cordero (1989) | USATF | 10.33 Q | +1.0 | 1v1 |
| 2 | McLean, Sean (1992) | USATF | 10.38 (10.378) Q | +1.8 | 1v2 |
| 3 | Asemota, Duan (1996) | Speed Academy Athletics Club | 10.38 (10.380) Q | +1.0 | 2v1 |
| 4 | Boateng, Bismark (1992) | Unattached - Ontario | 10.42 Q | +1.8 | 2v2 |
| 5 | Williams, Benjamin (1992) | Voleo Athletics | 10.45 Q | +1.0 | 3v1 |
| 6 | Walsh, Tahir (1994) | Antigua | 10.55 Q | +1.8 | 3v2 |
| 7 | Marcano, Andre (1986) | Trinidad | 10.46 q | +1.0 | 4v1 |
| 8 | N'doye, El-Hadj François (1989) | C.A. LaSalle | 10.59 (10.582) q | +1.0 | 5v1 |
| 9 | Robinson, Lucanus (1996) | Kilomaîtres De Lasalle | 10.59 (10.586) | +1.8 | 4v2 |
| 10 | Muteba, Lionel Tshimanga (1990) | C.A. LaSalle | 10.64 | +1.8 | 5v2 |
| 11 | Glor, Luxon (1997) | Winnipeg Optimist Athletics | 10.65 | +1.8 | 6v2 |
| 12 | Molango, Francis (1992) | Saint-Laurent Sélect | 10.74 | +1.0 | 6v1 |
| 13 | Pilipili, Hento (1995) | C. A. Université Laval | 10.91 | +1.0 | 7v1 |
| 14 | Adjibi, Eliezer (2000) | C.A.N.I. Athletics | 11.12 | +1.8 | 7v2 |
| 15 | Dodoo, Roland (1995) | Oakville Legion T.F.C. | 11.14 | +1.0 | 8v1 |
| --- | Garcia, Melique (1992) | Honduras | DNS | +1.8 | v2 |